Data related to an AEM electrolyzer operated under glycerol electro-oxidation conditions using Pt-Ag/C anodes, including a schematic figure of the electrolyzer assembly used for electrochemical measurements, polarization curves, HPLC-RID quantification of liquid products, associated quantification files used to derive product concentrations and selectivity, and catalyst characterization data (ICP for metal loading/composition and XRD patterns) for the materials used in the electrolyzer experiments.